Last week we reminded farmers and manure handlers that all stored manure can produce hazardous gases at levels of concern in some conditions. Some of these gases (like hydrogen sulfide [H2S]) are toxic and heavier than air and therefore are prone to sink to low areas like storage pits, sumps, or other depressions and accumulate to potentially LETHAL levels.
We also reported specifically on concerns we have with possible increased risk for exposure to high levels of H2S from long-term liquid manure storages used to store manure from barns where gypsum is used for cow bedding. These concerns are based on recent measurements taken by staff from the Benton fire department and the Yates County Soil and Water Conservation District (SWCD) where greater than 100 ppm H2S was measured at the edge of a long-term liquid manure storage structure. This level is identified as immediately dangerous according to the US Occupational Safety and Health Administration (OSHA).
The Yates County measurements are consistent with reports of high levels measured on at least one Pennsylvania farm where gypsum also was used for bedding and manure was stored. Gas concentrations are rapidly diluted with distance from the storage structure, so there should be little or no concern during agitation or clean out beyond the immediate farmstead.
Since last week it has come to our attention that gypsum is also being used by some New York State farmers as a bedding material in deep bedded pack barns. Deep bedded pack systems have the same anaerobic (little or no oxygen) conditions as long-term liquid manure storages – the conditions needed for the formation of H2S by microbes.
Therefore, the potential for human exposure to high levels of H2S is possible with bedded pack situations as well as long-term liquid manure storages. In fact, the opportunity for a farmer to be exposed to high levels of H2S may possibly be even higher with bedded packs, especially during clean-out. The packs are normally under roof, and enclosed barns may not provide enough air movement to maintain safe working conditions.
Late last week, staff from the Benton fire department and Yates County Soil and Water Conservation District (SWCD) measured more than 100 ppm H2S in a barn where a deep bedded back was being removed. Once again, gypsum had been used as part of the overall bedding material.
As a reminder, human exposure to hydrogen sulfide levels above 20 ppm can cause headaches, dizziness, and fatigue. According to OSHA, a concentration of 100 ppm H2S is immediately dangerous to life and health because the symptoms can make it difficult or impossible to escape from a dangerous situation. Levels over 100 ppm paralyze the olfactory nerve (sense of smell) causing the victim to not know they are breathing in the gas, and exposure at this level for 48 hours may cause death. At levels above 500 ppm, staggering and collapse can occur in 5 minutes, death after 30-60 minutes. Since we are finding random air samples over 100 ppm H2S, it is possible to have pockets of H2S near or in storage/bedded pack structures during agitation or clean-out that are at much higher levels.